The experimental results are compared with values calculated by means of the Wilson, UNIQUAC and NRTL equations utilizing parameters derived from the experimental s.l.e. The existence of a (solid + solid) first-order phase transition in hydrocarbons has been taken into consideration in the solubilit
Quaternary (liquid  +  liquid) equilibria for (water  +  ethanol  +  toluene  +  1,1-dimethylethyl methyl ether or 1,1-dimethylpropyl methyl ether) at the temperature 298.15 K
β Scribed by Yao Chen; ; Kazuhiro Tamura; ; Toshiro Yamada
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 145 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0021-9614
No coin nor oath required. For personal study only.
β¦ Synopsis
Liquid + liquid) equilibrium tie-lines were measured for the two quaternary systems
= 101.3 kPa. The experimental (liquid + liquid) equilibrium results have been satisfactorily correlated by modified and extended UNIQUAC models both with ternary and quaternary parameters in addition to binary ones.
π SIMILAR VOLUMES
Liquid + liquid) equilibrium data of (tert amyl ethyl ether + ethanol + water) were determined experimentally at T = (298. 15, 308.15, and 318.15) K. The experimental results were correlated with the NRTL and UNIQUAC equations. The correlations were made at each temperature and for the three tempera
Vapour + liquid) equilibrium data are presented for (methanol + ethyl tert-butyl ether) and (methanol + ethyl tert-butyl ether + toluene) at T = 328.15 K. The experimental results were measured by using a Boublik recirculation still. The binary results for (methanol + ethyl tert-butyl ether) and for
The excess molar enthalpies of (acetonitrile + 1,1-dimethylethyl methyl ether) and (methanol, or ethanol + acetonitrile + 1,1-dimethylethyl methyl ether) have been measured at T = 298.15 K and atmospheric pressure using a flow microcalorimeter. The experimental results are correlated with polynomial
Liquid + liquid) equilibrium data are presented for mixtures of {benzonitrile(1) + acetic acid or propanoic acid or butanoic acid or 2-methylpropanoic acid or pentanoic acid or 3-methylbutanoic acid(2) + water(3)} at T = 298.15 K. The relative mutual solubility of each of the carboxylic acids is hig