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Quasi-degenerate rayleigh-schrödinger perturbation theory with hermitean model hamiltonian

✍ Scribed by Vladimír Kvasnička; Alexej Holubec


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
598 KB
Volume
32
Category
Article
ISSN
0009-2614

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✦ Synopsis


A methbd for the construction of ;h& hermitaan'tiodel hakiltonian in &a framework of the quasidegenerate Rayleigh-SchCdinpr @ertuxbation theory is kuggesterj. The approach of a model hamiltonian is bati on the assunption that ifit is ~kqmE.=d in a chosen fmitedimension~ model space it will yield eigenvalues of the origin&l hzmiltonian in the entire H&ert space, For a unitary operator tra'nsforming ihe unperturbti~stite vectors onto the prturbed rtite vectors, md P model-interaction operator, the pcrh\rbo~oncxp3nsionformSe are developed.

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