Copper(H) mesoporphyrin IX dimethyl ester in methylcyclohesane solution shows at 77 I; a single-line ESK spectrum ascribable to an agsrcgted species. The luminescence of the a== oOre\_atc is confirmed by the absorption, emission. and escitation spectra and also its yield and lifetime ;Lre compared v
Quartet luminescence from copper porphyrins
โ Scribed by B.E. Smith; M. Gouterman
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- English
- Weight
- 297 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Coupling of an unpaired d electron to the porphyrin phosphorescent triplet gives rise to a YripdoubIet" and a quartet state. Luminescence from Cu porphin and Cu octdkylporphin is fargel-tripdoublet at liquid nitrogen temperature and quartet at liquid hydrogen tempcrnture. while Cu tetrnphenylprphin is quartet at both temperatures.
๐ SIMILAR VOLUMES
Rccwcd 77 t\ugust 198 I The CSR spcclr~ of Cu(ll) mcsoporphyrm IX dlmcthyl esw m loluenc solution at 77 ii rcvealcd the formatIon of rhc tnple~ SLIIC dlmer. Thu lummrscencc of IIIC dlmcr ws conlirmcd by lhe absorpllon, cmlsslon. and cw~l~t~on spectra.