A Wheel-Shaped Single-Molecule Magnet of
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Satoshi Koizumi; Masayuki Nihei; Takuya Shiga; Motohiro Nakano; Hiroyuki Nojiri;
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Article
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2007
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John Wiley and Sons
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English
⚖ 541 KB
## Abstract The reaction of __N__‐(2‐hydroxy‐5‐nitrobenzyl)iminodiethanol (=H~3~(5‐NO~2~‐hbide)) with Mn(OAc)~2~⋅ 4 H~2~O in methanol, followed by recrystallization from 1,2‐dichloroethane, yielded a wheel‐shaped single‐molecule magnet (SMM) of [Mn^II^~3~Mn^III^~4~(5‐NO~2~‐hbide)~6~]⋅5 C~2~H~4~Cl~2