The vibrational wavenumbers of 4-ethylimidazole were obtained from ab initio studies based on the density functional theory approach. The assignments of the theoretical wavenumbers obtained after scaling of the internal force constants were performed by comparison with the observed Raman and infrare
Quantum-statistical conductance theory of nonideal plasmas by use of the force-force correlation function method
✍ Scribed by G. Röpke; W. Ebeling; W.D. Kraeft
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 468 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0378-4371
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✦ Synopsis
Using the formalism of force-force correlation functions developed recently, the Spitzer formula for the conductance is generalized by taking into account the following effects: (1) dynamical screening; (2) ion-ion correlations by the ion structure factor; (3) deviations from Coulomb's interaction law; (4) influence of the Debye-Onsager relaxation effect; (5) quantum effects.
It is shown that all these effects decrease the conductance in comparison with the values predicted by the Spitzer theory and lead to a more reasonable agreement with the experimental data in the region/~ = e2/rDkT ~ 1 (rD -Debye radius).
Electron-electron interactions are treated by a systematic perturbative expansion of the force-force correlation function with the help of the Matsubara Green's function technique.
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