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Quantum Simulation of Nuclear Rearrangement in Electron Transfer Reactions

✍ Scribed by Chong Zheng, J. Andrew McCammon and Peter G. Wolynes


Book ID
123637240
Publisher
National Academy of Sciences
Year
1989
Tongue
English
Weight
639 KB
Volume
86
Category
Article
ISSN
0027-8424

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## Abstract Chemically induced dynamic nuclear polarization (CIDNP) observed during electron transfer (ET) reactions of tertiary amines such as DABCO (**1**) or Et~3~N (**2**) with a wide range of electron acceptors support the involvement of amine radical‐cations (__e.g.__, **1^.^**^**+**^ or **2^