Exact quantum mechanical transition probabilities have been calculated for the collinear reaction H f Fzfu = 0) + HF(u' < 11) + F by the state path sum method\_ The "best" extended LEPS surface of Jonathan et al. has been used. The results are in good agreemeat with experimental results and threedim
Quantum-mechanical study of the reaction Be + FH(υ = 0, 1) → BeF(υ′) + H
✍ Scribed by James F. Garvey; Jack A. Kaye; Aron Kuppermann
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 377 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Exacr quanium-mechanical calculauons for a collinear model of Ihe reaclion Be+ FH( u = 0.1) have been performed. Effects of rcager.t _sla~iooal and vibrational ucitarion on reaction probabililig and product ~LBI~ distributions are examined. Thcsc quantum rcsuhs show product state dlslnbutions which differ from those of quasi-classical lrajeclory calculations.
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