Quantum Mechanical Investigation of the Atmospheric Reaction CH 3 O 2 + NO
✍ Scribed by Lesar, Antonija; Hodošček, Milan; Drougas, Evangelos; Kosmas, Agnie M.
- Book ID
- 126888315
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 237 KB
- Volume
- 110
- Category
- Article
- ISSN
- 1089-5639
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## Abstract The atmospheric reaction NO~2~ + O~3~ → NO~3~ + O~2~ (1) has been investigated theoretically by using the MP2, G2, G2Q, QCISD, QCISD(T), CCSD(T), CASSCF, and CASPT2 methods with various basis sets. The results show that the reaction pathway can be divided in two different parts at the M
Pulse radiolysis was used to study the kinetics of the reactions of CH 3 C(O)CH 2 O 2 radicals with NO and NO 2 at By monitoring the rate of formation and decay of NO 2 295 K. using its absorption at the rate constants 400 and 450 nm k(CH C(O)CH O ϩ NO) ϭ (8 Ϯ 3 2 2 and were de-Ϫ12 Ϫ12 3 Ϫ1 Ϫ1 2) ϫ
## Abstract For Abstract see ChemInform Abstract in Full Text.