## Abstract Quantum mechanical calculations have been made of vibrational transition probabilities in the collinear collision of an inert gas atom with either CO~2~ or OCS. The dependence of the transition probability on the relative translational energy and the reduced mass is similar to that foun
Quantum mechanical calculations of vibrational transition probabilities in collinear atom-polyatom collisions
β Scribed by Aydin Berki; Sakir Erkoc
- Book ID
- 107732646
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 286 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
Rccewcd 15 hlnrch 1980 CaIculst~ons of quanta1 wbratronal transrtron probabrhtrrs are reported for colhnear colhons of CO2 utth He ond Kr for systematrc varrarrons of the anharmomc terms in the CO2 potermal Anhormomcrty decreases the probJbdrtres of V-T translttons and mcrcases the probabdrtrrs of V
An approlimatc approach is dcvelopcd to study the interfcrcncc of one-and twoquantum processes in collinear collisions of an atom and a harmonic oscillator. !n deriving an esplicit espression for vibrational transition probabilities, oncquantum processes arc trcatcd rigorously. while the contributio