Quantum effects in the dynamics of proton glasses
✍ Scribed by Dolinšek, J.; Arčon, D.; Zalar, B.; Pirc, R.; Blinc, R.; Kind, R.
- Book ID
- 118131628
- Publisher
- The American Physical Society
- Year
- 1996
- Tongue
- English
- Weight
- 98 KB
- Volume
- 54
- Category
- Article
- ISSN
- 1098-0121
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We have studied the quantum dynamics of proton transfer in the hydrogen-bonded complex HaOf-Ha0 using a previously computed three-dimensional potential energy surface. The two coordinates considered are the distance of the hydrogen atom from the O-O midpoint and the O-O distance, for a linear O-H-O
## Abstract The possible role of the nonlinear coupling on the character of the dynamics of particle transfer process is investigated. The analysis and solutions of the kinetic equation indicate that nonlinear coupling causes symmetry breaking of particle transfer potential and determines possible