Quantum effects in intramolecular energy transfer: the role of observations
โ Scribed by Ronni Kosloff; Stuart A. Rice
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 228 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
We show that when the nature of the preparation and observation processes are included in the quantum mechanical descrlptlon of intramolecular energy transfer, HeUer's argument for the nonergodlcity of Isolated degenerate quantum
๐ SIMILAR VOLUMES
A subclass of dynamical semigroups induced by the interaction of a quantum system with an environment is introduced. Such semigroups lead to the selection of a stable subalgebra of effective observables. The structure of this subalgebra is completely determined. 2000
An approlimatc approach is dcvelopcd to study the interfcrcncc of one-and twoquantum processes in collinear collisions of an atom and a harmonic oscillator. !n deriving an esplicit espression for vibrational transition probabilities, oncquantum processes arc trcatcd rigorously. while the contributio