✦ LIBER ✦

Quantum corrections to induced light scattering and the second virial coefficient of water and hydrogen sulfide

✍ Scribed by A. De Santis; A. Gregori

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 365 KB
Volume: 160
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(89)87555-4

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✦ Synopsis

Some model pair potentials of liquid water and hydrogen sulfide have been used for computing second virial coefficients, lowdensity values of depolarized lit scattering due to the dipole-induced-dipole (DID) mechanism, mean-square torques and mean-square forces versus temperature. The second virial coeffkient and depolarized scattering were corrected to account for quantum effects, which are found to be relevant in the case of water. The "MCY" water pair potential gives values of the second virial coefficient in good agreement with experiment, while computed and experimental values of the DID intensity disagree significantly. Possible reasons for this discrepancy are discussed.

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