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Quantum-chemical study of the reaction of pent-4-en-2-yn-1-ol with copper, zinc, and nickel sulfides

✍ Scribed by N. M. Ivanova; C. A. Shchelkunov; O. A. Malyshev


Book ID
111459330
Publisher
Springer
Year
2007
Tongue
English
Weight
77 KB
Volume
77
Category
Article
ISSN
1070-3632

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Embelin, 2,5-dihydroxy-3-undecyl-1,4-benzoquinone, has two intra-molecular hydrogen bonds between the quinone and hydroquinone groups present on the same ring. Therefore, it is expected to produce semiquinone radical in the oxidation as well reduction reactions. To investigate this aspect, kinetics