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Quantum chemical study of the nature of regioselectivity in reactions of 2,4,6-triazidopyridines withtert-butylphosphaacetylene

✍ Scribed by S. V. Chapyshev; V. M. Anisimov


Book ID
105528647
Publisher
Springer US
Year
1997
Tongue
English
Weight
646 KB
Volume
33
Category
Article
ISSN
0009-3122

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## Calculations on the thermochemistry of reactions between NH,' ions and EtHgX molecules (X = C1, Br, I) were performed by the MNDO method. The calculations showed the p i b l e existence of two stable isomers of composition [ EtHgX, NH, 1 + namely [ EtHgX -.HNH, 1 + and [ EtHg(NH,)XH I +. Proton