Quantum-Chemical Study of the Mechanism of Formation of 1- and 2-(Trimethylsilylmethyl)benzotriazoles
β Scribed by V. A. Shagun; E. I. Brodskaya; O. M. Trofimova; M. G. Voronkov
- Book ID
- 111609075
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2003
- Tongue
- English
- Weight
- 87 KB
- Volume
- 39
- Category
- Article
- ISSN
- 1070-4280
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π SIMILAR VOLUMES
## Abstract 1β(Trimethylsilylmethyl)benzotriazole is readily prepared from benzotriazole and chloromethyltrimethylsilane. It undergoes fluorideβcatalyzed desilylation with carbonyl compounds and forms an anion that can be alkylated and acylated readily and undergoes Peterson olefination. 1β(Cyclohe
The alcoholysis of 1,2-thiazetidine 1,1-dioxide has been investigated using ab initio and density functional theory at HF/6-31G\*, MP2/6-31G\*//HF/6-31G\* and B3LYP/6-31G\* levels. The geometries, energies and frequencies of all stationary points were calculated in detail. Solvent effects have been