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Quantum-chemical study of the influence of the solvent on the electronic structure and reactivity of molecules. 3. 1,2-proton shift in protonated benzene

✍ Scribed by I. A. Abronin; G. M. Zhidomirov

Book ID
112443877
Publisher
Springer
Year
1981
Tongue
English
Weight
437 KB
Volume
30
Category
Article
ISSN
1573-9171

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Study of the intrinsic and conformationa
Study of the intrinsic and conformational solvent effects on the chemical shift of the aldehydic proton in furfural and thiophenealdehyde
✍ JosΓ© FernΓ‘ndez BertrΓ‘n; Mario RodrΓ­guez πŸ“‚ Article πŸ“… 1974 πŸ› John Wiley and Sons 🌐 English βš– 233 KB

## Abstract The chemical shifts of the aldehydic proton in furfural, thiophenealdehyde and benzaldehyde have been measured in fourteen solvents. The correlation of the chemical shifts of thiophenealdehyde and benzaldehyde is excellent (__r__ = 0Β·996) while it is lower for furfural–benzaldehyde (__r