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Quantum-chemical study of the cleavage of the C-X bonds in the radical ions CH3X∸ (X=F, Cl, Br, I)

✍ Scribed by K. Ya. Burshtein; É. D. German

Book ID
112449594
Publisher
Springer
Year
1988
Tongue
English
Weight
419 KB
Volume
37
Category
Article
ISSN
1573-9171

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Bond strengths of the gas-phase cluster
Bond strengths of the gas-phase cluster ions X− (CS2)n (X = F, Cl, Br and I)
✍ Kenzo Hiraoka; Susumu Fujimaki; Kazuo Aruga; Shinichi Yamabe 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 467 KB

Thermodynamic quantities, AH:\_ ,,\* and AS:\_ ,,", for the clustering reactions, X-(CSI),\_,+CSz=X-(CS,),, X=F, Cl, Br and I, were measured with a pulsed electron-beam high-pressure mass spectrometer. A large binding energy, 35.0 kcal/mol, for F-...CS2 has been obtained, whereas those for other X-.