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Quantum chemical study of electronic structure of an intermediate in allylic rearrangement of 3-methyl-1-penten-4-yn-3-ol

✍ Scribed by V. M. Staroverov; T. A. Selyukova; L. A. Sleta; O. M. Tsyguleva


Book ID
112408436
Publisher
Springer
Year
1984
Tongue
English
Weight
255 KB
Volume
18
Category
Article
ISSN
0091-150X

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An intermediate structure between the benzenoid and cis-quinoid form of the title compound was trapped in solid-state tautomerization with the aid of OAHÁ Á ÁO type intermolecular H-bonds leading to multi-point self-recognition. X-ray crystallographic study reveals that an interesting extended struc