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Quantum-chemical studies of catalysts immobilized on silica. The complex Cu(OSiH3)2·2H2O as a model of catalytically active polycopperphenylsiloxanes

✍ Scribed by V. V. Smirnov; E. N. Golubeva; M. M. Levitskii


Publisher
Springer
Year
2000
Tongue
English
Weight
398 KB
Volume
49
Category
Article
ISSN
1573-9171

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Hydroesterification of cyclohexene using
✍ Andrea Vavasori; Luigi Toniolo; Gianni Cavinato 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 194 KB

The hydroesterification of cyclohexene is catalyzed by a preformed Pd(PPh 3 ) 2 (TsO) 2 complex I in methanol as solvent. The effect of PPh 3 , TsOH, and water on the TOF has been evaluated. The system I/PPh 3 /TsOH = 1/6/8, in the presence of 800 ppm of H 2 O, at 373 K and under 2.0 MPa of CO leads