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Quantum-chemical modeling of the mechanism of autocatalytic dehydrochlorination of PVC

✍ Scribed by V. M. Yanborisov; S. S. Borisevich


Publisher
Springer
Year
2005
Tongue
English
Weight
301 KB
Volume
41
Category
Article
ISSN
0040-5760

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The chloroallyl group contents of PVC and its low molecular weight fractions, soluble in chloroform or acetone, have been determined on the assumption that the reaction of AgNO~ with labile chlorine atoms occurs only with the allylic chlorines. Their amount is highest in the low molecular weight fra