I t is shown that cyclic oxides can be anionically polymerized if the lowest vacant molecular orbital (LVMO) of a C, atom contains a region which can effectively overlap by the electronic cloud of the anionic active centre. This means that LVMO must be a-symmetrical and a t least one of the C, atoms
✦ LIBER ✦
Quantum-chemical investigation of the formation of reaction centers during anionic polymerization with electron transfer
✍ Scribed by N. E. Kruglyak; T. É. Lipatova
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1980
- Tongue
- English
- Weight
- 389 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0022-4766
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Correlation between the electronic struc
✍
N. M. Geller; Yu. Ye. Eizner; V. A. Kropachev
📂
Article
📅
1985
🏛
John Wiley and Sons
🌐
English
⚖ 277 KB
👁 2 views
Chemical and spectroscopical evidence fo
✍
Asensio, Gregorio ;González Núñez, Elena ;Rodrigo, Maria José ;Varea, Teresa
📂
Article
📅
1989
🏛
Wiley (John Wiley & Sons)
🌐
English
⚖ 273 KB
👁 2 views
Formation of semiquinone radical in the
✍
Ravi Joshi; Tapan K. Ghanty; Tulsi Mukherjee
📂
Article
📅
2009
🏛
Elsevier Science
🌐
English
⚖ 638 KB
Embelin, 2,5-dihydroxy-3-undecyl-1,4-benzoquinone, has two intra-molecular hydrogen bonds between the quinone and hydroquinone groups present on the same ring. Therefore, it is expected to produce semiquinone radical in the oxidation as well reduction reactions. To investigate this aspect, kinetics