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Quantum chemical conformational analysis and X-ray structure of 4-methyl-3-thiosemicarbazide

✍ Scribed by Candee C. Chambers; Edet F. Archibong; Sam M. Mazhari; Ali Jabalameli; Jeffrey D. Zubkowski; Richard H. Sullivan; Edward J. Valente; Christopher J. Cramer; Donald G. Truhlar


Book ID
114142301
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
441 KB
Volume
388
Category
Article
ISSN
0166-1280

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Quantum chemical conformational analysis
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The potential energy surface of 4-methyl-3-indole acetic acid IAA was investigated via RHFr6-31G\* calculations. Five symmetry-unique local minima with syn-periplanar orientation of the COOH group are present. In contrast, unsubstituted IAA and 4-Cl-IAA have only four such minima. The shape of the e