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Quantum chemical calculations of stability constants: study of ligand effects on the relative stability of Pd(II)–peptide complexes

✍ Scribed by Elkin Tílvez; Natalia Díaz; M. Isabel Menéndez; Dimas Suárez; Ramón López


Publisher
Springer
Year
2010
Tongue
English
Weight
487 KB
Volume
128
Category
Article
ISSN
1432-2234

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The new mixed phosphane-phosphite ligands 1 and 2, derived from 3,3Ј-di-tert-butyl-2,2Ј-dihydroxy-5,5Ј-dimethoxybiphenyl and (S)-binaphthol, respectively, reacted with [Rh(COD)(THF) 2 ]CF 3 SO 3 to give the compounds [Rh(COD)(1)]CF 3 SO 3 and [Rh(COD)(2)]CF 3 SO 3 in which the ligands 1 and (S)-2 ar