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Quantum chemical calculation of the barrier for tunneling of hydrogen in hydrogen abstraction from methane by methyl

โœ Scribed by Asish K. Chandra; E. J. Padma Malar; Debasis Sen Gupta


Book ID
118286219
Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
511 KB
Volume
41
Category
Article
ISSN
0020-7608

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Comment: A re-evaluation of the rate con
โœ H.-X. Zhang; M. H. Back ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 212 KB ๐Ÿ‘ 1 views

The rate constant for abstraction of hydrogen from isobutane by methyl radicals has been re-examined making use of new measurements at temperatures above 660 K. Most of the data over the temperature range 300-855 K can be accommodated by the following values for the rate constants for abstraction fr