A model of the quantum return dynamics based on a scaling perspective on energy flow and localization of eigenstates is used to describe corrections to the RRKM theory of unimolecular dissociation. The scaling perspective addresses systems described by a local random matrix model for the Hamiltonian
Quantum chaos and random matrix theory — Some new results
✍ Scribed by U. Smilansky
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 569 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0167-2789
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✦ Synopsis
New insight into the correspondence between quantum chaos and random matrix theory is gained by developing a sermclassical theory for the autocorrelation function of spectral determinants. We study in particular the unitary operators which are the quantum versions of area preserving maps. The relevant random matrix ensembles are the circular ensembles. The resulting semiclassical expressions depend on the symmetry of the system with respect to time reversal, and on a classical parameter/z = tr U -1 where U is the classical one-step evolution operator. For system without time reversal symmetry, we are able to reproduce the exact random matrix predictions in the limit/z --+ 0. For systems with time reversal symmetry we can reproduce only some of the features of random matrix theory. For both classes we obtain the leading corrections in /z. The semiclassical theory for integrable systems is also developed, resulting in expressions which reproduce the theory for the Poissonian ensemble to leading order in the semiclassical limit.
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