✦ LIBER ✦
Quantitative theory of chemically induced dynamic nuclear polarisation in high magnetic fields
✍ Scribed by A. L. Buchachenko; Sh. A. Markarian
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 326 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0749-1581
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Further development of the diffusional model of the radical pair is suggested. A function is proposed for the exponential distribution of the diffusional trajectories of the radicals in a radical pair. By this function, the differences in the populations of nuclear spin levels in the molecules are calculated for the S, T and U precursor pairs.
The equations which express the relationship between the theoretically calculated population differences and the experimentally determined enhancement coefficients are derived.