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Quantitative solvent extraction from neutral aqueous nitrate media of silver(I) against lead(II) with a new calix[4]arene-based bipyridine podand

✍ Scribed by Jean-Bernard Regnouf-de-Vains; Jean-Olivier Dalbavie; Roger Lamartine; B Fenet


Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
148 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis


A new calix [4]arene-based podand incorporating two 2,2%-bipyridine and two benzyl units in alternate positions at the lower rim was shown to quantitatively extract silver(I) from neutral aqueous solutions containing a mixture of lead and silver nitrates. The corresponding AgPF 6 complex was synthesised and characterised.