Quantitative Evaluation of Anion–π Interactions in Solution
✍ Scribed by Guzmán Gil-Ramírez; Eduardo C. Escudero-Adán; Jordi Benet-Buchholz; Pablo Ballester
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 534 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
## Abstract Several complexes of tropylium (**1**) with anions are optimized at the RI‐MP2(full)/6‐31++G\*\* level of theory. This binding unit can interact very favorably with anions, and it combines the strength of the electrostatic interaction with the directionality of the anion–π interaction.
## Abstract Crystal structures of the copper(i) complexes 1^X^, 2, and 3 of a series of tridentate ligands L1^X^, L2, and L3, respectively (L1^X^: __p__‐substituted derivatives of __N__,__N__‐bis[2‐(2‐pyridyl)ethyl]‐2‐phenylethylamine; X=H, Me, OMe, Cl, NO~2~; L2: __N__,__N__‐bis[2‐(2‐pyridyl)ethyl