Quantitative determination of the concentrations of 13C15N chemical bonds by double cross-polarization NMR
✍ Scribed by Jacob Schaefer; E.O Stejskal; J.R Garbow; R.A McKay
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 365 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0022-2364
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Both 13C-and 15N-REDOR experiments were performed to determine the '3C-'5N interatomic distance in [ I-"C]N-acetyl-Pro-[ '5N]GIy-Phe crystal and to evaluate the inter-or intra-molecular dipolar contributions leading to its errors. The interatomic distance was determined to be 3.43 8, after removing
## Abstract To determine the feasibility of using NMR to study the inactivation of cytochromes P‐450 by dichloroacetamide‐containing mechanism‐based inactivators, ^13^C, ^15^N‐enriched compounds were synthesized, modeling adducts between the nucleophilic side‐chains of cysteine, lysine, serine (thr