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Quantitative description of electrophilic aromatic substitution reactions from the standpoint of perturbation theory

โœ Scribed by A. I. D'yachenko; A. I. Ioffe; V. I. Faustov; O. M. Nefedov

Book ID
112442311
Publisher
Springer
Year
1979
Tongue
English
Weight
120 KB
Volume
28
Category
Article
ISSN
1573-9171

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Homoazulene electrophilic aromatic subst
Homoazulene electrophilic aromatic substitution reactions. Parallels to the chemistry of azulene
โœ Lawrence T. Scott; Chris A. Sumpter; Mitsunori Oda; Ihsan Erden ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 274 KB

Homoazulene (l), like azulene (2), undergoes Friedel-Crafts acylation under exceptionally mild conditions (no Lewis acid) and exhibits the same site-selectivity as azulene; sequential disubstitution takes place exclusively at the a-and a'-positions in the smaller ring.