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Quantitative Analysis of Ti−O−Si and Ti−O−Ti Bonds in Ti−Si Binary Oxides by the Linear Combination of XANES

✍ Scribed by Kim, Won Bae; Choi, Sun Hee; Lee, Jae Sung


Book ID
126051815
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
131 KB
Volume
104
Category
Article
ISSN
0022-3654

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29Si and17O NMR investigations on Si−O−T
✍ Dagobert Hoebbel; Thomas Reinert; Helmut Schmidt 📂 Article 📅 1996 🏛 Springer 🌐 English ⚖ 816 KB

The structural units in diphenylsilanediol/titanium-isopropoxide solutions with molar ratio Si:Ti between 1 :O. 1 and I:5 were examined by means of 29Si and "0 NMR. The main component in solutions with molar ratio Si/Ti = 1 :O. 1 is the chain-like octaphenyltetrasiloxanediol. With increasing Ti-iso