Quantitative Analysis and Structure Determination of Styrene/Methyl Methacrylate Copolymers by Pyrolysis Gas Chromatography
✍ Scribed by Wang, Frank Cheng-Yu; Smith, Patrick B.
- Book ID
- 121332965
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 230 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0003-2700
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The end groups of styrene-methyl methacrylate (St-MMA) copolymers polymerized radically with 2,2Ј-azobisisobutyronitrile (AIBN) as an initiator, which are difficult to characterize even by NMR, were investigated by pyrolysis-gas chromatography. On the resulting pyrograms, characteristic products tha
Pyrolysis gas chromatographic investigations have been carried out on copolymers of styrene with trimethyl-vinyl-silane and of styrene with dimethyl-phenyl-vinyl-silane, in order to study the mechansims of thermal degradation and the copolymer structures. We have identified the pyrolysis products an