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Quantitative accounting for the medium effect at the catalytic decomposition of H2O2in hydrophilic solvents

✍ Scribed by A. P. Pokutsa; R. G. Makitra; D. S. Maksim; E. Ya. Pal’chikova

Book ID
111460176
Publisher
Springer
Year
2009
Tongue
English
Weight
186 KB
Volume
79
Category
Article
ISSN
1070-3632

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📜 SIMILAR VOLUMES

“Complex” versus “free radical” mechanis
“Complex” versus “free radical” mechanism for the catalytic decomposition of H2O2 by ferric ions
✍ Mordechai L. Kremer 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 771 KB

Kinetic and spectrophotometric measurements made during the Fe3+ ion catalyzed decomposition of H,O, have been analyzed using the computer simulation method. Improved values of the rate constants of the "complex scheme" and of the molar absorptivities of the intermediates were obtained: k,/Kw = 4.9