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Quantification of cis and trans influences in [PtX(PPh3)3]+ complexes. A 31P NMR study

✍ Scribed by Luca Rigamonti; Michele Rusconi; Carlo Manassero; Mario Manassero; Alessandro Pasini


Book ID
108138354
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
483 KB
Volume
363
Category
Article
ISSN
0020-1693

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πŸ“œ SIMILAR VOLUMES


A tungsten-183 NMR study of cis and tran
✍ Laurence Carlton; Avril Emdin; Andreas Lemmerer; Manuel A. Fernandes πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 213 KB

2 ) 3 (trans isomer only). The 183 W chemical shift (obtained by indirect detection using 31 P) is found to be related to the PR 3 ligand parameters Ξ½ and ΞΈ (Tolman electronic factor and cone angle, respectively) for the cis isomers and to Ξ½ (but only poorly to ΞΈ ) for the trans isomers. The 183 W-3