Qualitative supercritical fluid extraction coupled to capillary gas chromatography

✍ Scribed by Levy, Joseph M. ;Rosselli, Athos C. ;Boyer, David S. ;Cross, Kathryn

• Publisher: John Wiley and Sons
• Year: 1990
• Tongue: English
• Weight: 489 KB
• Volume: 13
• Category: Article
• ISSN: 0935-6304
• DOI: 10.1002/jhrc.1240130607

✦ Synopsis

Abstract

The usefulness and ease of utilizing supercritical fluid extraction (SFE) directly coupled to capillary gas chromatography (GC) as quantitative or qualitative analytical problem‐solving tools will be demonstrated. As an alternative to conventional liquid solvent extractions, SFE presents itself as a means to achieve high extraction efficiencies of different compounds in complex solid matrices in very rapid tims frames. Moreover, SFE has an additional advantage of being able to achieve distinct extraction selectivities as a function of the solubilizing power of the supercritical fluid extracting phase. For on‐line SFE/GC, the extraction effluent is directly transferred to the analytical chromatograph. On‐line SFE/GC involves the decompression of pressurized extraction effluent directly into a heated, unmodified capillary split injection port of the GC. In this respect, SFE introduction into GC can be used as an alternative means of GC injection, comparable to such modes of injection as pyrolysis and thermal desorption. This paper will show applications of SFE/GC where mass spectrometric detection together with flame ionization detection was used for component identification from environmental, tobacco, and petroleum matrices.