We present a theoretical account of the Jahn-Teller (JT) and pseudo-Jahn-Teller (PJT) effects in the photoelectron spectrum of cyclopropane. The PJT interactions between the two JT split X 2 E 0 and Ã2 E 00 electronic states of the cyclopropane radical cation are examined. Nuclear dynamical simulati
✦ LIBER ✦
Qualitative picture of the Jahn-Teller effect in the spectrum of a nonrigid XY3molecule
✍ Scribed by A. V. Burenin
- Book ID
- 110125423
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2000
- Tongue
- English
- Weight
- 80 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0030-400X
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## Abstract The photodetachment spectroscopy of B anion is theoretically studied with the aid of a quantum dynamical approach. The theoretical results are compared with the available experimental photoelectron spectra of B. Both B and B~3~ possess D~3__h__~ symmetry at the equilibrium configuration