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Quadrupole interaction in (NH4)2FeF5 · H2O

✍ Scribed by L.K. Hanamoto; C.S.M. Partiti


Book ID
104167022
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
312 KB
Volume
101
Category
Article
ISSN
0038-1098

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✦ Synopsis


The quadrupole splitting of (NH&FeF5 -HZ0 was measured in the 79-340K temperature range. A strong dependence of temperature was observed. This effect was explained in terms of thermally activated reorientations of the NH: ion. Our data had resulted in an activation energy of (750 f 30) K. A comparison with results previously reported of (NH&FeC15H20 is presented.


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D.C. susceptibility and zero field Mössbauer spectroscopy measurements are used to characterize the low-temperature magnetism of \(\alpha-\mathrm{Rb}_{2} \mathrm{FeF}_{5} \cdot \mathrm{H}_{2} \mathrm{O}\) and \(\alpha-\mathrm{Cs}_{2} \mathrm{FeF}_{5} \cdot \mathrm{H}_{2} \mathrm{O}\). The compounds