The role of alkyl substitution on the sp
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Kazumi Toriyama; Kaoru Matsuura; Keichi Nunome
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Article
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1990
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Elsevier Science
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English
โ 475 KB
The role of alkyl substitution on the electronic structure of cyclohexane radical cation was investigated with low-temperature matrix ESR and semiempirical MO calculations. It was found that the unpaired electron, which is originally delocalized throughout the cyclohexane ring, tends to be confined