Al solid state NMR allows the isotropic chemical shift and quadrupolar interaction parameters for the four crystallographitally inequivalent AIOs sites in kyanite, a polymorph of AlsSiOs, to be deduced. Magic angle spinning at two fields ( 11.7 and 17.55 T), satellite transitions and double rotation
✦ LIBER ✦
Quadrupole and chemical shift interactions of 27Al in aluminium molybdate from satellite transition magic angle spinning NMR
✍ Scribed by G. Kunath-Fandrei; T.J. Bastow; C. Jaeger; M.E. Smith
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 423 KB
- Volume
- 234
- Category
- Article
- ISSN
- 0009-2614
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## Abstract A simple procedure is presented for the determination of the asymmetry parameter of the electric field gradient, the quadrupole coupling constant, the second‐order quadrupolar shift and the isotropic chemical shift of quadrupolar nuclei with half‐integer spin directly from the experimen