Chemical shifts of GaAs and InGaAs were observed by solid-state h&h-resolution NMR. The spectrum of GaAs appeared as a single peak but that of InGaAs consisted of an intense narrow peak and a weak broad one which appeared at =10-U ppm slightly higher field from the former.
Quadrupolar nutation NMR on a compound semiconductor gallium-arsenide
β Scribed by J. Takeuchi; H. Nakamura; H. Yamada; E. Kita; A. Tasaki; T. Erata
- Book ID
- 104357827
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 482 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0926-2040
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β¦ Synopsis
Lattice defects in a compound semiconductor, gallium-arsenide are evaluated by two-dimensional nutation nuclear magnetic resonance. Especially in the case of indium doped gallium-arsenide, analysis of the nutation patterns indicates that the electric field gradient exists in the whole crystal. Asymmetry parameters and quadrupolar coupling constants are determined as approximately 1.0 and 93 kHz, respectively. These results suggest that the whole crystal is under slight strain. Through this work, it is demonstrated that a two-dimensional nutation nuclear magnetic resonance is the useful method to investigate the lattice defects in gallium-arsenide.
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## Abstract The effect of the cluster shape on the magnitudes of the static dipole (hyper)polarizabilities of large gallium arsenic clusters built from 72 atoms is presented and discussed. Also, the performance of conventional and long range corrected density functionals is assessed on the predicti