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Quadricyclane and norbornadiene radical cations in silicalite: comparison with freon matrices

✍ Scribed by Mary V. Barnabas; David W. Werst; Alexander D. Trifunac


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
347 KB
Volume
206
Category
Article
ISSN
0009-2614

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Low-temperature study of radical cations
✍ K.R. Cromack; D.W. Werst; M.V. Barnabas; A.D. Trifunac πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 557 KB

We have observed quadricyclane and norbomadiene radical cations in different pentasil type zeolites by EPR spectroscopy after 4 K in situ electron beam irradiation of samples in the EPR spectrometer. We report the first evidence for matrix isolation of the quadricyclane radical cation. It is stable