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Quadratic Nonlinearity of One- and Two-Electron Oxidized Metalloporphyrins and Their Switching in Solution

โœ Scribed by Wahab, Abdul; Bhattacharya, Mily; Ghosh, Sampa; Samuelson, A. G.; Das, Puspendu K.


Book ID
125850735
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
194 KB
Volume
112
Category
Article
ISSN
0022-3654

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One-electron oxidation and demetalation
โœ Haim Levanon; P. Neta ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 356 KB

Formation of cation radicals by pulse radiolysis of metalloporphyrins and chlorophyll a in 1,2dichIoroethane is reported. Demetalation of the metalloporphyrin by radiolytically produced HCl is also observed. Rate constants for demetalation of ZnTPP and Chl a are 1 .I X IO8 and = 3 X IO8 h!-' s-I\_ O