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Pyrrolodiazines. 6. Palladium-Catalyzed Arylation, Heteroarylation, and Amination of 3,4-Dihydropyrrolo[1,2- a ]pyrazines †

✍ Scribed by Castellote, Isabel; Vaquero, Juan J.; Fernández-Gadea, Javier; Alvarez-Builla, Julio


Book ID
120000039
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
198 KB
Volume
69
Category
Article
ISSN
0022-3263

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Abtra~ The structure of 3,4-dihydropyrrolo[ 1,2-a]pyrazine and its N-protonated form is studied by ab initio calculations. Examples of the re, activity of this poorly studied system are presented in which it is shown that the imino moiety does not react with dienes but does undergo inter-and intramo

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Structure and Chemistry of 3,4-Dihydropyrrolo( 1,2-a)pyrazine. -The structure of title compound (I) and its N-protonated form is studied by ab initio calculations. The cyclic imino nitrogen can be quaternized to furnish azomethine ylide precursors which undergo inter-and intramolecular 1,3-dipolar

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