Pyrrolo[3,2-c][1,2,5]benzotriazocine: A new ring system
β Scribed by Alessandra Passannanti; Patrizia Diana; Paola Barraja; Antonino Lauria; Girolamo Cirrincione; Francesco Mingoia
- Book ID
- 102340363
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1998
- Tongue
- English
- Weight
- 198 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0022-152X
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β¦ Synopsis
Abstract
A nucleophilic substitution reaction in the pyrrole series, achieved by a neutral nucleophile, led to the key intermediate 7 which by reduction and successive diazotization afforded the new ring system pyrrolo[3,2βc][1,2,5]benzotriazocine 9 in good yield.
π SIMILAR VOLUMES
## Abstract Derivatives of the new ring system pyrrolo[3,4β__e__][1,2,3] triazolo[1,5β__a__]pyrimidine **6** were prepared in high yields in one step by reaction of 3βazidopyrrole **3** and substituted acetonitriles. Compound **6b** rearranged, upon heating in dimethyl sulfoxide in the presence of