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Pyrrolizidine Alkaloids by Intramolecular Palladium-Catalyzed Allylic Alkylation: Synthesis of (.+-.)-Isoretronecanol.

✍ Scribed by Sebastien Lemaire; Giuliano Giambastiani; Guillaume Prestat; Giovanni Poli

Publisher
John Wiley and Sons
Year
2004
Weight
9 KB
Volume
35
Category
Article
ISSN
0931-7597

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Asymmetric catalysis / Allylic alkylation / 1-Methyl-5-(1Ј-methylpent-2Ј-ynyl)barbituric acid / Palladium catalysts / Chiral phosphane imine ligands / Methohexital / Anesthetic dose Allylation of 1-methyl-5-(1Ј-methylpent-2Ј-ynyl)barbituric Chiral phosphane imine ligands are a successful class of c