Pyrrole formation from a (1-azabutadiene)tricarbonyliron(0) complex
โ Scribed by Timothy N. Danks; Susan E. Thomas
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 128 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
The (l-azabutadiene)tricarbonyliron(O) complex 2 formed by selective complexation of the E ?! isomer of the stereoisoieric mixture of 1-azabutadienes 1 reacts smoo hly with methyl-lithium to give the 1,2,3,5_tetrasubstTtuted pyrrole 2.
๐ SIMILAR VOLUMES
A simple procedure for the synthesis of 1,2,3-trideutero amines, alcohols and hydrocarbons from the reaction between lithium aluminiumdeuteride and tricarbonyliron(0) complexes of 1-heterodienes and homo-dienes is reported.
A new class of p-conjugated organic compounds, 1-aryl-2,5-bis[5-(tricyanoethenyl)-2-thienyl]pyrroles that form goldlike lustrous crystals with a high melting point were obtained. The molecules in these crystals are arranged in a planar sheet to get close to each other via the intermolecular C HโขโขโขN