𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Pyrolysis of β-hidroxy sulfoxides. II. Synthesis of allylic alcohols

✍ Scribed by Junzo Nokami; Kazuo Ueta; Rokuro Okawara

Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
116 KB
Volume
19
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

A novel synthesis of epoxides and allyli
A novel synthesis of epoxides and allylic alcohols from carbonyl compounds through α, β-epoxy sulfoxides
✍ Tsuyoshi Satoh; Youhei Kaneko; Koji Yamakawa 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 203 KB

Treatment of s,8-epoxy sulfoxides, easily prepared from carbonyl compounds with 1 equivalent of n-butyllithium at -100 'C gave the desulfinated epoxides in good yields. The similar a,8-epoxy sulfoxides having arylmethyl group at a-position, on treatment with excess n-butyllithium at -70 "C afforded

A stereoselective synthesis of β,γ-disub
A stereoselective synthesis of β,γ-disubstituted allylic alcohols of z-configuration
✍ Mitsuhisa Tamura; Gohu Suzukamo 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 190 KB

Reaction of alkyllithiums 1 with isoprene epoxide 2 gives B,y-disubstituted allylic alcohols 2 of Z-configuration. The reaction of \*-lithiotricyclene as alkyllithium gives o-santalol 5, which is one of the main constituents in East Indian sandalwood oil.