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Pyrolysis of polyacrylonitrile and related polymers—IX: Copolymers of acrylonitrile with vinyl chloride, vinylidene chloride and α-chloroacrylonitrile

✍ Scribed by N. Grassie; R. McGuchan


Book ID
107753289
Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
559 KB
Volume
9
Category
Article
ISSN
0014-3057

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📜 SIMILAR VOLUMES


Pyrolysis of polyacrylonitrile and relat
✍ N. Grassie; R. McGuchan 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 556 KB

Vinyl acetate exerts some blocking effect on the nitrile group oligomerization which dominates the initial pyrolytic processes in polyacrylonitrile, but the other comonomers studied allow more extensive nitrile reaction and do not effectively block the reaction. Decomposition of the vinyl esters, ta

Pyrolysis of polyacrylonitrile and relat
✍ N. Grassie; R. McGuchan 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 597 KB

Comparison of the thermal behaviour of polyacrylonitrile with that of a-substituted polymers (polymethacrylonitrile, poly(a-phenyl acrylonitrile), poly(a-chloroacrylonitril¢) and poly(vinylidene cyanide)) shows that there is much less tendency for oligomerization of the nitrile groups in the substit