Pyrolysis of Aryl Azides. VI. Identification of Neighbouring Group Effects in Pyrolysis of Azidopyridines and Azidoquinolines
โ Scribed by Dyall, LK; Wah, WM
- Book ID
- 121225712
- Publisher
- Commonwealth Scientific and Industrial Research Organisation Publishing
- Year
- 1985
- Tongue
- English
- Weight
- 778 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0004-9425
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The activating effects of a number of unsaturated groups and a cyclopropyl group have been evaluated in a solvent free system by determining the absolute rate constants, and energies and entropies of activation in the vapor phase pyrolysis of secondary and tertiary esters of the type RC(R'CH,)OAc wh
The pyrolysis kinetics of two phenylaminobutyl acetates were determined in a static system over the temperature range 359.7-399.6 ยฐC and the pressure range 23.8-95 Torr. The reactions, in vessels seasoned with allyl bromide and in the presence of the free radical inhibitor toluene, are homogeneous a