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Pyrolysis of 3-azidopropionitrile studied by UV photoelectron and matrix-isolation IR spectroscopies: Formation of ketenimine H2CCNH

✍ Scribed by Pinto, R.M.; Dias, A.A.; Levita, G.; Rodrigues, P.; Barros, M.T.; Dyke, J.M.; Costa, M.L.


Book ID
120299928
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
965 KB
Volume
1025
Category
Article
ISSN
0022-2860

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✍ Kindermann, Markus Karl ;Kowski, Klaus ;Muchall, Heidi M. ;Rademacher, Paul 📂 Article 📅 1993 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 613 KB

## Abstract The PE spectra of the 4,5‐dihydro‐3__H__‐pyrazoles 1, 2, of 2,5‐dihydro‐1,3,4‐oxadiazole 3, and 2,5‐dihydro‐1,3,4‐thiadiazole 4 have been recorded. Based on HAM/3, MNDO, AM1, and PM3 calculations, the ionization potentials have been assigned to molecular orbitals. The gas‐phase thermoly